As the industry standard for NOx control
technology, selective catalytic
reduction systems (SCR) converts toxic
nitrogen oxides with the aid of a
catalyst into diatomic nitrogen and
water. Mixing the exhaust air with a
gaseous reagent, anhydrous ammonia,
aqueous ammonia or urea, while passing
the homogenous mixture over a catalyst
bed the nitrogen oxides are absorbed.
Proper size, composition and space
velocity are three integral elements in
the loading of a catalyst, where as the
temperature range, viscosity and
anticipated NOx levels are the basis for
the design. Throughout this process,
Ammonia slip is carefully controlled,
meeting environmental requirements.
Afterwards the prepared reagent and
control system are integrated into plant
operations.
Stoichiometric reaction using either
anhydrous ammonia or aqueous ammonia
process is:
4NO + 4NH3 + O2 → 4N2 + 6H2O
2NO2 + 4NH3 + O2 → 3N2 + 6H2O
NO + NO2 + 2NH3 → 2N2 + 3H2O
The reaction for urea instead of
anhydrous ammonia or aqueous ammonia
process is:
4NO + 2(NH2)2CO + O2 → 4N2 + 4H2O + 2CO2
The ideal reaction has an optimal
temperature range between 674.33 °F and
836.33 °F, but can operate from 440.33
°F to 836.33 °F with longer residence
times. The minimum effective temperature
depends on the various fuels, gas
constituents and catalyst geometry.